Title of article
Control of diastereoselectivity in the aldolization of methyl phenylacetate
Author/Authors
Pinheiro، نويسنده , , Sergio and Lima، نويسنده , , Marcelo B and Gonçalves، نويسنده , , Clara B.S.S and Pedraza، نويسنده , , Sérgio F and de Farias، نويسنده , , Florence M.C، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
2
From page
4033
To page
4034
Abstract
The aldolization of methyl phenylacetate with benzaldehyde in several conditions was studied. While the use of LDA in THF–HMPA gave the anti-aldol, the dibutylboron triflate furnished the syn-aldol in high diastereoselectivity (syn:anti=97:3).
Keywords
dibutylboron triflate , phenylacetate , aldol , diastereoselection
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637724
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