Author/Authors :
Coterَn، نويسنده , , José M. and Chiara، نويسنده , , José L. and Fernلndez-Mayoralas، نويسنده , , Alfonso and Fiandor *، نويسنده , , José M. del Valle، نويسنده , , Nuria، نويسنده ,
Abstract :
The glycosidation of sordaricin with deoxy sugars derivatives was studied under acid-promoted conditions and by anomeric O-alkylation with sordaricin triflate. In both methods, an important effect of added ammonium salts on the stereoselectivity of the glycosidation was observed.
Keywords :
carbohydrates , Antifungals , Glycosidation , stereocontrol