A syn selective dihydroxylation of cyclic allylic trichloroacetamides using catalytic osmium tetroxide
Author/Authors :
Blades، نويسنده , , Kevin and Donohoe، نويسنده , , Timothy J and Winter، نويسنده , , Jonathan J.G and Stemp، نويسنده , , Geoffrey، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Pages :
4
From page :
4701
To page :
4704
Abstract :
A range of cyclic allylic trichloroacetamides has been synthesised. Dihydroxylation utilising catalytic osmium tetroxide and quinuclidine-N-oxide monohydrate as the re-oxidant in dichloromethane yields diols with good levels of syn selectivity.
