Title of article :
Stereoselective electrochemical transformation of alkylidenecyanoacetates and malonate into (E)-3-substituted-2-cyanocyclopropane-1,1,2-tricarboxylates
Author/Authors :
Elinson، نويسنده , , Michail N and Feducovich، نويسنده , , Sergey K and Starikova، نويسنده , , Zoya A and Olessova، نويسنده , , Olga S and Vereshchagin، نويسنده , , Anatolii N and Nikishin، نويسنده , , Gennady I، نويسنده ,
Abstract :
Electrolysis of malonate and alkylidenecyanoacetates in alcohols in the presence of sodium bromide in an undivided cell results in the stereoselective formation of (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates in 75–85% yields.
Keywords :
stereoselectivity , Electrochemical reactions , Catalysis , Cyclopropanes
