Title of article
Total synthesis of coronafacic acid through 6-endo-trig mode intramolecular cyclization of an enone-aldehyde to a hydrindanone using samarium(II) iodide
Author/Authors
Sono، نويسنده , , Masakazu and Hashimoto، نويسنده , , Atsuko and Nakashima، نويسنده , , Katsuyuki and Tori، نويسنده , , Motoo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
5115
To page
5118
Abstract
Coronafacic acid has been synthesized from a hydrindanone prepared by a 6-endo-trig mode cyclization reaction of the enone-aldehyde with samarium(II) iodide. The stereochemistry of the hydrindanone was controlled by the coordinated samarium species resulting in cis in respect of the hydroxyl group at C-4 and the juncture proton at C-3a.
Keywords
Biologically active compounds , Esters , indanes/hydrindanes , carboxylic acids and derivatives
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638158
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