Title of article
Radical reactions catalysed by ruthenium(II) complexes with anionic carborane phosphine ligands: Kharasch addition to olefins and controlled polymerisation
Author/Authors
Simal، نويسنده , , François and Sebille، نويسنده , , Sophie and Demonceau، نويسنده , , Albert and Noels، نويسنده , , Alfred F and Nuٌez، نويسنده , , Rosario and Abad، نويسنده , , Mar and Teixidor، نويسنده , , Francesc and Viٌas، نويسنده , , Clara، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
5347
To page
5351
Abstract
Ruthenium-carborane complexes 1–3 mediated the Kharasch addition of carbon tetrachloride across olefins with high yields which markedly depended on the catalyst and the substrate used. In addition, the atom transfer radical polymerisation of methyl methacrylate could be carried out in a highly controlled way.
Keywords
Catalysis , ruthenium and compounds , radicals and radical reactions , olefins , polymerisation , Carboranes
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638206
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