Author/Authors :
Simal، نويسنده , , François and Sebille، نويسنده , , Sophie and Demonceau، نويسنده , , Albert and Noels، نويسنده , , Alfred F and Nuٌez، نويسنده , , Rosario and Abad، نويسنده , , Mar and Teixidor، نويسنده , , Francesc and Viٌas، نويسنده , , Clara، نويسنده ,
Abstract :
Ruthenium-carborane complexes 1–3 mediated the Kharasch addition of carbon tetrachloride across olefins with high yields which markedly depended on the catalyst and the substrate used. In addition, the atom transfer radical polymerisation of methyl methacrylate could be carried out in a highly controlled way.
Keywords :
Catalysis , ruthenium and compounds , radicals and radical reactions , olefins , polymerisation , Carboranes