• Title of article

    Interaction of t-butyllithium and triphenylmethylenephosphoranes

  • Author/Authors

    Korth، نويسنده , , Karsten and Sundermeyer، نويسنده , , Jِrg، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    5461
  • To page
    5464
  • Abstract
    NMR experiments show that a directed ortho-metalation occurs at one of the aromatic rings of triphenylmethylenephosphoranes (Ph3P-CHR, R=H, Me) when the phosphorus ylide is treated with 1 equiv. t-BuLi. If pre-coordination of t-BuLi is inhibited by a sterically demanding and electron-withdrawing substituent (R=SiMe3) no metalation is observed.
  • Keywords
    NMR data , lithiation , ylides , Phosphoranes
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1638230

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1638230