Author/Authors :
Carda، نويسنده , , Miguel and Castillo، نويسنده , , Encarnacion Montecino-Rodriguez، نويسنده , , Santiago and Marco، نويسنده , , J.Alberto، نويسنده ,
Abstract :
A very short and stereoselective synthesis of the non-natural enantiomer of malyngolide from l-erythrulose is described. Key features of the synthesis are the Felkin–Anh diastereoselective allylation of a polyoxygenated ketone and the allylation/metathesis/allylic oxidation protocol recently described by our group.