Title of article
Stereoselective preparation of Z-trisubstituted alkylidene cyclic carbonates via palladium-catalyzed carboncarbon bond formation
Author/Authors
Toullec، نويسنده , , Patrick and Carbayo Martin، نويسنده , , Aranzazu and Gio-Batta، نويسنده , , Monica and Bruneau، نويسنده , , Christian and Dixneuf *، نويسنده , , Pierre H، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
5527
To page
5531
Abstract
Alkylidene cyclic carbonates bearing a Z-trisubstituted exocyclic double bond have been stereoselectively prepared in good yields for the first time from methylene cyclic carbonates, resistant to the classical Heck reaction, on treatment with aryl iodides, CF3CO2Ag and palladium catalyst, under conditions which tolerate (sp2)CBr bonds.
Keywords
Palladium catalysis , silver trifluoroacetate , Cyclic carbonates
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638243
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