• Title of article

    Stereoselective preparation of Z-trisubstituted alkylidene cyclic carbonates via palladium-catalyzed carboncarbon bond formation

  • Author/Authors

    Toullec، نويسنده , , Patrick and Carbayo Martin، نويسنده , , Aranzazu and Gio-Batta، نويسنده , , Monica and Bruneau، نويسنده , , Christian and Dixneuf *، نويسنده , , Pierre H، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    5527
  • To page
    5531
  • Abstract
    Alkylidene cyclic carbonates bearing a Z-trisubstituted exocyclic double bond have been stereoselectively prepared in good yields for the first time from methylene cyclic carbonates, resistant to the classical Heck reaction, on treatment with aryl iodides, CF3CO2Ag and palladium catalyst, under conditions which tolerate (sp2)CBr bonds.
  • Keywords
    Palladium catalysis , silver trifluoroacetate , Cyclic carbonates
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1638243