Title of article
Conjugate addition of zincates derived from ketone α,β-dianions to enones. An access to unsymmetrical 1,6-diketones
Author/Authors
Ryu، نويسنده , , Ilhyong and Ikebe، نويسنده , , Masanobu and Sonoda، نويسنده , , Noboru and Yamato، نويسنده , , Shin-ya and Yamamura، نويسنده , , Go-hei and Komatsu، نويسنده , , Mitsuo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
5689
To page
5692
Abstract
The conjugate addition of organozincates derived from ketone α,β-dianions to enones was examined. Good yields of unsymmetrical 1,6-diketones were obtained by this reaction. A mixed zincate consisting of the dianion and methyllithium in a 2:1 ratio gave results which were comparable to those of an unmixed dianion zincate.
Keywords
dianion zincate , conjugate addition , unsymmetrical 1 , 6-diketone , ketone ? , ?-dianion
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638276
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