Reverse Brook rearrangement of 2-alkynyl trialkylsilyl ether. Synthesis of optically active (1-hydroxy-2-alkynyl)trialkylsilane
Author/Authors :
Sakaguchi، نويسنده , , Kazuhiko and Fujita، نويسنده , , Masato and Suzuki، نويسنده , , Hiroyuki and Higashino، نويسنده , , Masato and Ohfune *، نويسنده , , Yasufumi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Pages :
4
From page :
6589
To page :
6592
Abstract :
A new method for the synthesis of optically active α-hydroxyalkynylsilane 3 is described. The key step of the conversion to 3 was the use of the reverse Brook rearrangement of the 2-alkynyl silyl ether 2.
