Title of article
Reactions of acylzirconocene chloride with nucleophiles: bimodal reactivity at β- and acyl carbons of α,β-unsaturated acylzirconocene chloride
Author/Authors
Hanzawa، نويسنده , , Yuji and Narita، نويسنده , , Kensuke and Kaku-uchi، نويسنده , , Akito and Taguchi*، نويسنده , , Takeo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
7525
To page
7528
Abstract
Reactions of α,β-unsaturated acylzirconocene chloride with nucleophiles showed novel bimodal reactivity at the β- and acyl carbons depending upon the nucleophile employed, and the formation of ketone α,β-dianionic species was also observed.
Keywords
Metallacycles , acylzirconocene chloride , ketone ? , ?-dianion , Michael additions , Cuprate
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639049
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