• Title of article

    Regio- and stereoselective thermal cycloaddition of α-aryl-N-phenylnitrones to 16-dehydropregnenolone acetate: π-facial selective addition of the minor rotamers of the nitrones

  • Author/Authors

    Girdhar، نويسنده , , Navdeep K. and Ishar، نويسنده , , M.P.S.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    7551
  • To page
    7554
  • Abstract
    Thermal cycloaddition of α-aryl-N-phenylnitrones to the C16C17 π-bond in 16-dehydropregnenolone-3β-acetate (1) involves only the minor rotamer (E-form) of the nitrones and occurs regio-, stereo- and π-facial-selectively to afford steroido[16,17-d]isoxazolidines (3) in high yield.
  • Keywords
    nitrone , stereoselective , 3-dipolar cycloaddition , 1 , regioselective , Pregnenolone
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1639062