Title of article :
Reaction of nitric oxide with benzyl cyanide to yield a bis-diazeniumdiolated imidate
Author/Authors :
Arnold، نويسنده , , Ernst V and Keefer، نويسنده , , Larry K and Hrabie، نويسنده , , Joseph A، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
The reaction of nitric oxide with benzyl cyanide in the presence of sodium methoxide forms the bis-diazeniumdiolated imidate, PhC[C(OMe)NH][N(O)NO−Na+]2. This compound decomposes in acidic media to yield nitric oxide, nitrous oxide and 2-oximino-2-phenylacetic acid methyl ester.
Keywords :
nitrogen oxides , Nitriles , imidic acids and derivatives , diazenes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters