Title of article
Immobilization of asymmetric multifunctional catalysts on an insoluble polymer
Author/Authors
Matsunaga، نويسنده , , Shigeki and Ohshima، نويسنده , , Takashi and Shibasaki، نويسنده , , Masakatsu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
6
From page
8473
To page
8478
Abstract
Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported LaZn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee.
Keywords
solid-phase synthesis , asymmetric synthesis , linked-BINOL , Michael reaction , asymmetric catalyst
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639593
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