Title of article
Strategy for contra-thermodynamic radical-chain epimerisation of 1,2-diols using polarity-reversal catalysis
Author/Authors
Dang، نويسنده , , Hai-Shan and Roberts، نويسنده , , Brian P.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
8595
To page
8599
Abstract
Polarity-reversal catalysis by thiols has been applied to provide an efficient method for the conversion of appropriate 1,2-diols into less or similarly stable diastereoisomers by epimerisation of their acetonides under radical-chain conditions.
Keywords
radicals and radical reactions , thiols , Diols , isomerisation , carbohydrates , Catalysis
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639686
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