• Title of article

    An expeditious route to phosphorus heterocycles based on ring-closing metathesis

  • Author/Authors

    Timmer، نويسنده , , Mattie S.M and Ovaa، نويسنده , , Huib and Filippov، نويسنده , , Dmitri V and van der Marel، نويسنده , , Gijs A. and van Boom، نويسنده , , Jacques H، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    8635
  • To page
    8638
  • Abstract
    A convenient route for the synthesis of phosphorus diolefinic templates starting from the bifunctional reagent bis(diisopropylamino)vinylphosphine is presented. Ring closing olefin metathesis on this type of diene substrate revealed that the newly developed 4,5-dihydro-imidazol-2-ylidene ruthenium benzylidene complex 4 is in all aspects superior to the previously developed Grubbs’ catalyst 1.
  • Keywords
    ring-closing metathesis , Phosphitylation , Phosphorus heterocycles
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1639710