Author/Authors :
Bradley، نويسنده , , Alexander Z and Link، نويسنده , , A.James and Biswas، نويسنده , , Kaustav and Kahne، نويسنده , , Daniel and Schwartz، نويسنده , , Jeffrey and Jones Jr.، نويسنده , , Maitland and Zhu، نويسنده , , Zhendong and Platz، نويسنده , , Matthew S، نويسنده ,
Abstract :
Photolysis of ‘naphtho-o-carborane’ in the presence of excellent hydrogen donors such as 1,4-cyclohexadiene leads to quantitative double hydrogen abstraction. Other molecules, including supercoiled DNA, similarly act as hydrogen atom donors towards photolyzed naphtho-o-carborane. A diradical intermediate is proposed.
