Title of article
Molar scale electrosynthesis of ethyl-2,2-difluoro-2-trimethylsilylacetate, a difluoromethylene building block precursor
Author/Authors
Clavel، نويسنده , , Philippe and Biran، نويسنده , , Claude and Bordeau، نويسنده , , Michel and Roques، نويسنده , , Nicolas and Trévin، نويسنده , , Stéphane، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
8763
To page
8767
Abstract
Ethyl-2,2-difluoro-2-trimethylsilylacetate has been prepared by electrolysis of ethyl-2-chloro-2,2-difluoroacetate in one step, at a molar scale, in the presence of a large excess of chlorotrimethylsilane. The transfer of the ethyl-2,2-difluoroacetate moiety to various electrophiles has been achieved.
Keywords
Electrosynthesis , ethyl-2 , 2-difluoro-2-trimethylsilylacetate , CF2COOEt-building block
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639801
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