Title of article
A novel and efficient method for the silylation of alcohols with methallylsilanes catalyzed by Sc(OTf)3
Author/Authors
Suzuki، نويسنده , , Takeshi and Watahiki، نويسنده , , Tsutomu and Oriyama، نويسنده , , Takeshi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
8903
To page
8906
Abstract
Reaction of alcohols with methallylsilanes in the presence of a catalytic amount of Sc(OTf)3 provides efficiently the corresponding alkyl silyl ethers. By using microencapsulated (MC) Sc(OTf)3, which can be easily recovered and reused, yields of alkyl silyl ethers are improved and the work-up process after completion of the reaction is considerably simplified.
Keywords
silylation of alcohols , Sc(OTf)3 , Catalytic , Silyl ethers , MC Sc(OTf)3 , methallylsilanes , Chemoselectivity
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639914
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