Title of article :
Highly enantioselective copper-catalyzed substitution of allylic chlorides with diorganozincs
Author/Authors :
Dübner، نويسنده , , Frank and Knochel، نويسنده , , Paul، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
The new ferrocenyl ligand 1i allows the performance of a highly enantioselective copper catalyzed SN2′-allylic substitution of allylic chlorides with diorganozincs, providing substituted products with enantiomeric excesses of up to 98%.
Keywords :
Copper , enantioselective allylation , Zinc , asymmetric synthesis , Ferrocene
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters