Title of article
Total synthesis of (±)-6-deoxycastanospermine: an application of the addition of organoboronates to N-acyliminium ions
Author/Authors
Batey، نويسنده , , Robert A and MacKay، نويسنده , , D.Bruce، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
9935
To page
9938
Abstract
An efficient synthesis of (±)-6-deoxycastanospermine is reported, using a diastereoselective coupling of organoboronates with N-acyliminium ions as the key step. The construction of the indolizidine ring system is completed using a subsequent reductive amination reaction.
Keywords
Stereochemistry , N-acyliminium ion , reductive amination , N-heterocycle , alkaloid , boron
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1640585
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