• Title of article

    Total synthesis of (±)-6-deoxycastanospermine: an application of the addition of organoboronates to N-acyliminium ions

  • Author/Authors

    Batey، نويسنده , , Robert A and MacKay، نويسنده , , D.Bruce، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    9935
  • To page
    9938
  • Abstract
    An efficient synthesis of (±)-6-deoxycastanospermine is reported, using a diastereoselective coupling of organoboronates with N-acyliminium ions as the key step. The construction of the indolizidine ring system is completed using a subsequent reductive amination reaction.
  • Keywords
    Stereochemistry , N-acyliminium ion , reductive amination , N-heterocycle , alkaloid , boron
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1640585