Title of article
Oxidative cleavage of unsaturated 1,2-diols using chiral lead-tetracarboxylates obtained by in situ metathesis
Author/Authors
Maria and Ignacio Candela Lena، نويسنده , , José Ignacio and Sesenoglu، نويسنده , , ضzge and Birlirakis، نويسنده , , Nicolas and Arseniyadis، نويسنده , , Siméon، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
21
To page
24
Abstract
A combination of an acetate metathesis/cascade transformations process, providing ring enlarged systems decorated with a chiral auxiliary, is presented. The use of a chiral carboxylic acid, such as (S)-2-acetoxypropionic acid, gives diastereomeric mixtures when performed in the racemic series, offering the possibility of a chemical resolution.
Keywords
Ring expansion , acetate metathesis , chiral carboxylic solvents , cascade transformations
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1640861
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