Title of article :
Radical-chain redox rearrangement of cyclic benzylidene acetals to benzoate esters in the presence of thiols
Author/Authors :
Roberts، نويسنده , , Brian P and Smits، نويسنده , , Teika Pakalns، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
Cyclic benzylidene acetals derived from 1,2- and 1,3-diols undergo an efficient ring-opening redox rearrangement to give benzoate esters in the presence of a peroxide initiator and a thiol, which acts as a polarity-reversal catalyst to promote the radical-chain reaction.
Keywords :
radicals and radical reactions , Catalysis , thiols , Diols , Rearrangements , carbohydrates
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
