Title of article :
On the ring-contraction of 1,4-dithiins to 1,3-dithiole derivatives
Author/Authors :
Andreu ، نويسنده , , Raquel and Gar??n، نويسنده , , Javier and Orduna، نويسنده , , Jes?s and Royo، نويسنده , , José M، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
The effect of different factors (pKa of the base, nature of the counterion and dissociation of the ion pairs) on the course of the base-induced rearrangement of 1,4-dithiins to 1,3-dithiole derivatives is discussed. Ab initio calculations account for the driving force of these isomerisations.
Keywords :
Sulfur heterocycles , thiafulvalenes , isomerisation , dithioles
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
