Title of article :
A facile, strain-induced 1,2-aryl migration in 5,6-diarylacenaphthenes
Author/Authors :
Pritchard، نويسنده , , Robin G. and Steele، نويسنده , , Melanie and Watkinson، نويسنده , , Michael and Whiting، نويسنده , , Andrew، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
Treatment of 5,6-di(3-tert-butyl-4-methoxyphenyl)acenaphthene 3 with boron trichloride leads to rapid formation of the 1,2-aryl migration product 4. The rearrangement is catalysed directly by boron trichloride and not by a proton, and results from the strain added by the tert-butyl functions of 3.
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
