Title of article
The first total synthesis of (+)-rogioloxepane A
Author/Authors
Matsumura، نويسنده , , Ryuji and Suzuki، نويسنده , , Toshio and Hagiwara، نويسنده , , Hisahiro and Hoshi، نويسنده , , Takashi and Ando، نويسنده , , Masayoshi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
1543
To page
1546
Abstract
The first total synthesis of (+)-rogioloxepane A is described. The α,ω-trans-disubstituted oxepene skeleton was stereoselectively constructed via cyclization of the hydroxy epoxide promoted by the (Bu3Sn)2O/Zn(OTf)2 system. The proposed configurations of 6R and 13R were confirmed through this synthetic study.
Keywords
cyclization , natural products , oxepanes , medium-ring heterocycles
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1643277
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