Title of article :
Reductive coupling of aromatic oxims and azines to 1,2-diamines using Zn-MsOH or Zn-TiCl4
Author/Authors :
Kise، نويسنده , , Naoki and Ueda، نويسنده , , Nasuo Ueda، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
The reduction of aromatic aldoxims and azines with Zn in the presence of MsOH or TiCl4 afforded N,N′-unsubstituted 1,2-diamines in one-step. The reductive coupling with Zn-MsOH gave meso 1,2-diamines selectively, whereas dl 1,2-diamines were formed selectively by the reduction with Zn-TiCl4.
Keywords :
reductive coupling , Azine , 1 , 2-diamine , oxim
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
