Author/Authors :
M. Narendra Mallya، نويسنده , , M and Nagendrappa، نويسنده , , Gopalpur and Shashidhara Prasad، نويسنده , , J and Sridhar، نويسنده , , M.A and Lokanath، نويسنده , , N.K and Begum، نويسنده , , N.S، نويسنده ,
Abstract :
NOCl adds to cyclic vinylsilanes in a syn manner with NO+ bonding to the β-carbon and Cl− to the α-carbon, which is a reversal of the regiochemistry expected from the β-silicon effect. The adducts dimerize to a single diastereomer containing enantiomeric pairs and/or give secondary products on further reaction.
Keywords :
NOCl , vinylsilanes , silylated diazene dioxides , nitrososilanes
