Author/Authors :
Couturier، نويسنده , , Michel and Andresen، نويسنده , , Brian M and Tucker، نويسنده , , John L and Dubé، نويسنده , , Pascal and Brenek، نويسنده , , Steven J and Negri، نويسنده , , Joanna T، نويسنده ,
Abstract :
The scope of borane–amine adducts as reducing agents is broadened through palladium-catalyzed methanolysis capable of reducing a wide variety of functional groups. Hence, borane mediated reduction of a benzamide followed by a tandem methanolysis/hydrogenolysis of the resulting borane–benzylamine adduct allows chemoselective removal of an N-benzoyl in the presence of an O-benzoyl.
