Title of article
Nucleophilic reactions of propargyl acetates mediated by titanocene dichloride and magnesium
Author/Authors
Yang، نويسنده , , Fanglong and Zhao، نويسنده , , Gang and Ding، نويسنده , , Yu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
2839
To page
2841
Abstract
Reaction of Cp2TiCl2/Mg with propargyl acetates form allenyl titanium intermediates, which undergo nucleophilic addition reactions to aldehydes or ketones to give homopropargyl alcohols in high yields. Subsequent nucleophilic addition to acetonitrile and nucleophilic substitution with allyl bromide are also mentioned.
Keywords
homopropargyl alcohol , Titanocene , Magnesium
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644305
Link To Document