Author/Authors :
Blanco-Urgoiti، نويسنده , , Jaime and Casarrubios، نويسنده , , Luis V. Dominguez، نويسنده , , Gema and Pérez-Castells، نويسنده , , Javier، نويسنده ,
Abstract :
The synthesis of several natural products’ frameworks is carried out by means of a diastereoselective intramolecular Pauson–Khand reaction promoted by molecular sieves. Diastereoselectivity is achieved only if a coordinating group is present at a convenient distance from the alkene moiety. Naphthalenes can be obtained directly under refluxing toluene conditions.