Author/Authors :
Mizuno، نويسنده , , Kazuhiko and Sugita، نويسنده , , Hikaru and Hirai، نويسنده , , Takayoshi and Maeda، نويسنده , , Hajime and Otsuji، نويسنده , , Yoshio and Yasuda، نويسنده , , Masahide and Hashiguchi، نويسنده , , Mitsuhiro and Shima، نويسنده , , Kensuke، نويسنده ,
Abstract :
Irradiation of a benzene solution containing 1-diphenylvinylidene-2,2,3,3-tetramethylcyclopropane and an excess of acrylonitrile in the presence of Michlerʹs ketone afforded 2-cyano-1-diphenylvinylidene-4,4,5,5-tetramethylcyclopentane in high yield.
Keywords :
(3+2) photocycloaddition , vinylidenecyclopropane , electron-deficient alkene , vinylidenecyclopentane , 1 , 3-biradical