Title of article :
Titanocene(II)-promoted reaction of gem-dihalides possessing a terminal double bond. New intramolecular cyclopropanation
Author/Authors :
Fujiwara، نويسنده , , Tooru and Odaira، نويسنده , , Miho and Takeda، نويسنده , , Takeshi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
The Cp2Ti[P(OEt)3]2 1-promoted intramolecular reaction of gem-dihalides possessing a terminal double bond is described. The treatment of 6,6- and 7,7-dihalo-1-alkenes with 1 produced bicyclo[3.1.0]hexane and bicyclo[4.1.0]heptane derivatives, respectively.
Keywords :
halogens and compounds , titanium and compounds , Dehalogenation , Cyclopropanation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
