• Title of article

    Selective preparation of (Z)- and (E)-prop-1-enylamides from N-allylbenzamides

  • Author/Authors

    Pierre Ribéreau، نويسنده , , Pierre and Delamare، نويسنده , , Madeleine and Célanire، نويسنده , , Sylvain and Quéguiner، نويسنده , , Guy، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    3571
  • To page
    3573
  • Abstract
    A series of para-substituted N-allylbenzamides was submitted to isomerization under basic conditions. With LDA at −78°C, the corresponding (E)-N-(prop-1-enyl)benzamide was the major product. With n-butyllithium and the mixture warmed to 0°C, the (Z)-isomer was essentially furnished.
  • Keywords
    Isomerization , lithiation , Enamides , allylbenzamides
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1644875