Title of article
Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects
Author/Authors
Angelis، نويسنده , , Yiannis S and Hatzakis، نويسنده , , Nikos S. and Smonou، نويسنده , , Ioulia and Orfanopoulos، نويسنده , , Michael، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
3753
To page
3756
Abstract
The primary and β-secondary kinetic isotope effects in the oxidation of secondary alcohols with dimethyl dioxirane were measured. The substantial primary and the absence of a β-secondary kinetic isotope effect support a concerted mechanism for the title reaction.
Keywords
Dioxiranes , isotope effects , Mechanisms
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644999
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