Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects
Author/Authors :
Angelis، نويسنده , , Yiannis S and Hatzakis، نويسنده , , Nikos S. and Smonou، نويسنده , , Ioulia and Orfanopoulos، نويسنده , , Michael، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Pages :
4
From page :
3753
To page :
3756
Abstract :
The primary and β-secondary kinetic isotope effects in the oxidation of secondary alcohols with dimethyl dioxirane were measured. The substantial primary and the absence of a β-secondary kinetic isotope effect support a concerted mechanism for the title reaction.
