Title of article
A new pathway to chiral tetracyclic indolidines via Pauson–Khand reaction
Author/Authors
Tanimori، نويسنده , , Shinji and Fukubayashi، نويسنده , , Kouji and Kirihata، نويسنده , , Mitsunori، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
4013
To page
4016
Abstract
Reaction of enynes 1 and 3 with Co2(CO)8 in the presence of DMSO, NMO or TMANO as promoters produced tricyclic indolidine derivatives 5 and 7 stereoselectively in moderate to excellent yield. The stereochemistry at the C-7 position of the indolidines 5 and 7 was confirmed by their conversion into the bridged azacycles 10 and 13.
Keywords
Pauson–Khand reaction , asperparaline
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1645203
Link To Document