Title of article :
Sc(OTf)3-catalyzed C-glycosidation of glycals: a facile synthesis of allyl glycosides, glycosyl cyanides and glycosyl azides
Author/Authors :
Yadav، نويسنده , , J.S. and Reddy، نويسنده , , B.V.Subba and Chand، نويسنده , , Pratap K، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
The treatment of glycals with allyltrimethylsilane, trimethylsilyl cyanide and trimethylsilyl azide in the presence of catalytic amounts of Sc(OTf)3 gave the corresponding 2,3-unsaturated allyl glycosides, glycosyl cyanides and glycosyl azides in excellent yields with high α-selectivity.
Keywords :
3-unsaturated glycosides , 2 , glycals , C-glycosidation , Scandium triflate
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
