• Title of article

    Is diphenylboronium perchlorate in nitromethane ionic?

  • Author/Authors

    Kiyooka، نويسنده , , Syun-ichi and Fujiyama، نويسنده , , Ryoji and Kawai، نويسنده , , Takatomo and Fujimoto، نويسنده , , Hiroshi and Goh، نويسنده , , Kazuki، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    4151
  • To page
    4153
  • Abstract
    The 11B NMR chemical shift for diphenylboronium perchlorate was determined to be 46.02 ppm in CD3NO2. An ab initio calculation of the chemical shift (GIAO-HF/6-311+G(2d,p)//B3LYP/6-31+G(d)) indicated a value of 47.02 ppm. The agreement between the calculated and found values strongly suggests that the character of the BO bond is covalent with an ionic character.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1645320

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1645320