Title of article
Arylation of phosphoryl-stabilized carbanions with metal π-complexes of aryl chlorides and fluorides
Author/Authors
Artamkina، نويسنده , , Galina A and Sazonov، نويسنده , , Petr K and Beletskaya، نويسنده , , Irina P، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
4385
To page
4387
Abstract
The nucleophilic aromatic substitution of halogen in metal arene π-complexes η6-(ArF)Cr(CO)3 and [η6-(ArHal)FeCp]+[PF6]− (Hal=F,Cl) with phosphoryl-stabilized carbanions ZCH2P(O)(OEt)2 (Z=COOEt, CN) allows the synthesis of metal π-complexes of α-EWG-substituted arylmethylphosphonates in high yields.
Keywords
arylation , carbanions , ?6-arene metal ?-complexes , Phosphonates
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1645508
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