Author/Authors :
Keglevich، نويسنده , , Gyِrgy and Kِrtvélyesi، نويسنده , , Tamلs and Forintos، نويسنده , , Henrietta and Tamلs، نويسنده , , Annamلria and Ludلnyi، نويسنده , , Krisztina and Izvekov، نويسنده , , Vladiszlav and Tِke، نويسنده , , Lلszlَ، نويسنده ,
Abstract :
The [2+2] cycloaddition reaction of dimethyl acetylenedicarboxylate (DMAD) and the PO moiety of cyclic P-(2,4,6-triisopropylphenyl) phosphine oxides giving an entry to oxaphosphetes is of general value and extended to cyclic and alicyclic phosphine oxides with different trialkylphenyl substituents on the phosphorus atom. The structures of the products obtained by the [2+2] cycloaddition have been studied by semiempirical quantum chemical calculations
Keywords :
Phosphorus heterocycles , Phosphine oxides , theoretical studies , cycloaddition