• Title of article

    Facile formation of benzene from a novel cyclohexane derivative

  • Author/Authors

    Liu، نويسنده , , Xiadong and Zhang، نويسنده , , Guangtao and Verkade، نويسنده , , John G، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    4449
  • To page
    4451
  • Abstract
    Upon acidification, benzene forms at room temperature from the novel 1,3,5-cis-trisubstituted cyclohexane wherein the substituents are the azido phosphine cage moieties N3P(MeNCH2CH2)3N. The dominant reaction in the decomposition of this unusually thermally stable intermediate in the presence of HA is the formation of nitrogen and the salt [H2NP(MeNCH2CH2)3N]A in addition to benzene. Evidence for a transannulated cage intermediate is presented.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1645557

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1645557