Ion amperometry at the interface between two immiscible electrolyte solutions in view of realizing the amperometric ion-selective electrode

This article reviews the development in ion amperometry at the interface between two immiscible electrolyte solutions (ITIES) in view of realizing the amperometric ion-selective electrode (ISE). The concept of polarizability of ITIES in a multi-ion system is outlined. Principle aspects of ion amperometry at ITIES are discussed including the use of amperometry as a tool for the clarification of the ion sensing mechanism, and for determining the concentrations of ions in the solution. The reference is made to recent amperometric measurements at the supported liquid membrane (SLM) and polymer composite liquid membranes (PCLM), which, together with the micro-hole supported ITIES, appear to be particularly suitable for realization of the amperometric ISE.