• Title of article

    Preparation of silanethiols by reaction of silanes with triphenylphosphine sulfide and with alkanethiols

  • Author/Authors

    Cai، نويسنده , , Yudong and Roberts، نويسنده , , Brian P، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    4581
  • To page
    4584
  • Abstract
    Silanes react with triphenylphosphine sulfide by a radical-chain mechanism to give the corresponding silanethiols in good yield. Silanethiols are similarly formed when silanes react with tert-dodecanethiol. Enantiomerically pure (S)-ButMePhSiH gave racemic silanethiol with Ph3PS, but with tert-dodecanethiol silanethiol with an ee up to 60% has been obtained, although in low chemical yield.
  • Keywords
    silicon and compounds , phosphorus and compounds , thiols , radicals and radical reactions
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1645665

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1645665