• Title of article

    Synthesis and transformation of a novel methano[60]fullerene having a formyl group

  • Author/Authors

    Hamada، نويسنده , , Masahiro and Hino، نويسنده , , Tetsuo and Kinbara، نويسنده , , Kazushi and Saigo، نويسنده , , Kazuhiko، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    5069
  • To page
    5071
  • Abstract
    The reaction of [60]fullerene with a dimethylsulfonium α-formylalkylide gave a novel methano[60]fullerene having a formyl group at the bridge-head carbon. This 2,2-[60]fulleroalkanal was readily converted into a variety of N-aryl-2,2-[60]fulleroaldimines by condensation with aromatic amines; one of them showed efficient quenching of the fluorescence of the [60]fullerene core, due to a photoinduced intramolecular electron transfer.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1646009