Title of article
A deepseated carbodication rearrangement. Limited paths because of charge repulsion
Author/Authors
Taeschler، نويسنده , , Christoph and Sorensen، نويسنده , , Ted S، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
5339
To page
5341
Abstract
The 1,5-manxyl dication undergoes a very specific skeletal rearrangement to give the 3,7-dimethylbicyclo[3.3.1]nona-3,7-diyl dication. The corresponding manxyl monocation is also labile but forms an apparent myriad of rearrangement products. This result is an indication that the dication rearrangement involves many fewer branching reactions.
Keywords
cation rearrangements , superacid solutions , carbodication , manxyl , MO calculations
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1646208
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