Title of article
Synthesis of the first fluorinated cantharidin analogues
Author/Authors
Essers، نويسنده , , Michael and Wibbeling، نويسنده , , Birgit and Haufe، نويسنده , , Günter، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
5
From page
5429
To page
5433
Abstract
Fluorinated cantharidin analogues (4–7) have been synthesized for the first time. The key step in each synthesis is an exo-selective Diels–Alder reaction of furan with the appropriate fluorinated maleic anhydride. 17O NMR measurements of 5–7 and the corresponding non-fluorinated parent compounds were undertaken to show the influence of the fluorine substituent(s) on the electronic properties of the oxygen atoms.
Keywords
Diels–Alder reaction , fluorinated cantharidin analogues , fluorinated maleic anhydrides , furan , 17O NMR
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1646292
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