Title of article :
Aminium hexachloroantimonate salts: a latent source of antimony pentachloride
Author/Authors :
Vincenzo Ciminale، نويسنده , , Francesco and Lopez، نويسنده , , Luigi and Farinola، نويسنده , , Gianluca M. and Sportelli، نويسنده , , Stefano، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
Cyclization of an adamantylidene-based olefin induced by aminium hexachloroantimonate salts under a nitrogen atmosphere revealed that oxidative activation by these salts may be due to SbCl6−, which in combination with an oxidant counter-ion provides SbCl5 as the true reactive species.
Keywords :
Antimony pentachloride , aminium salts , oxidative activation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters