Title of article
First enantioselective total synthesis of both enantiomers of lancifolol. Correlation: absolute configuration/specific rotation
Author/Authors
Galano، نويسنده , , Jean-Marie and Audran، نويسنده , , Gérard and Monti، نويسنده , , Honoré، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
6125
To page
6128
Abstract
The first enantioselective total synthesis of both enantiomers of lancifolol has been accomplished using a Z-stereoselective Peterson olefination and a palladium-catalyzed cross-coupling reaction as key steps. This approach allows us to correlate the relationship between absolute configuration and specific rotation, to date both unknown.
Keywords
Olefination , stereocontrol , natural products , coupling reactions , asymmetric synthesis
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1646808
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