Title of article
Deuterium exchange mediated by an iridium–phosphine complex formed in situ
Author/Authors
Ellames، نويسنده , , George J and Gibson، نويسنده , , Jennifer S and Herbert، نويسنده , , John M and Kerr، نويسنده , , William A. and McNeill، نويسنده , , Alan H، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
6413
To page
6416
Abstract
Bis(triorganophosphine)(cyclooctadiene)iridium(I) tetrafluoroborates, 2, are readily generated in situ and utilised for the exchange of deuterium into a variety of aromatic substrates. The efficiencies of deuterium exchange using 2 formed in this way are comparable to those observed in exchange processes where the isolated pre-catalysts were used.
Keywords
Iridium complexes , deuterium exchange , Isotope exchange
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1646979
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